Title : Nanostructured zirconia-based ceramic material fabricated by an oscillatory pressure sintering process
Abstract:
The actual strength of ceramics is much lower than their theoretical value due to considerable flaws appearing during powder consolidation. A straightforward approach to improve their fracture strength is to minimize the quantity and size of flaws within ceramics. Here, we report a sintering strategy to consolidate ultrastrong ceramics by introducing oscillatory pressure. We have fabricated a fully dense ZrO2 ceramics contained 3mol.% Y2O3, ZrO2 ceramics strengthened by 20wt.% Al2O3 with a three-point bending strength of up to 1.81 GPa, 2.1 GPa, respectively, which are the strongest zirconia-based ceramics yet achieved. Strengthening of the material is based on adopting a dynamic oscillatory pressure during sintering to remove various flaws (including agglomerated-pores and micro-pores), strengthen grain boundaries (mainly owing to the formation of a high number density of coherent grain boundaries structure). We believe that this sintering process can be applied to manufacture other ceramics with extremely high strength for structural applications.
Audience take away:
• we report a sintering strategy to consolidate ultrastrong ceramics by introducing oscillatory pressure.
• Strengthening of the material is based on adopting a dynamic oscillatory pressure during sintering to remove various flaws and strengthen grain boundaries.
• We believe that this sintering process can be applied to manufacture other ceramics with extremely high strength for structural applications.